Hydrazine Oxidation Electrocatalysis

Tomer Y. Burshtein; Yakov Yasman; Lisa Muñoz-Moene; José H. Zagal; David Eisenberg

doi:10.1021/acscatal.3c05657

Hydrazine Oxidation Electrocatalysis

Tomer Y. Burshtein, Yakov Yasman, Lisa Muñoz-Moene, José H. Zagal, David Eisenberg

Chemistry

Research output: Contribution to journal › Review article › peer-review

Abstract

The electro-oxidation of hydrazine is important for direct hydrazine fuel cells and for fundamental understanding of electrocatalysis in the nitrogen cycle. In this Review, we discuss electrocatalysis of the hydrazine oxidation reaction (HzOR), spanning a vast range of metal surfaces, nanoparticles, atomically dispersed ions, organometallic macrocycles, and enzymes. Emphasis is given to structure-activity correlations and reactivity descriptors, including the formulation of the Zagal principle, an electrochemical corollary of the Sabatier principle. In addition, we identify overarching themes that span the different subfields of HzOR electrocatalysis, hoping to inspire cross-disciplinary research avenues.

Original language	English
Pages (from-to)	2264-2283
Number of pages	20
Journal	ACS Catalysis
DOIs	https://doi.org/10.1021/acscatal.3c05657
State	Accepted/In press - 2024

Keywords

alternative fuels
electrocatalysis
hydrazine
nitrogen cycle
Sabatier principle
single atom catalysts

ASJC Scopus subject areas

Catalysis
General Chemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1021/acscatal.3c05657

Cite this

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title = "Hydrazine Oxidation Electrocatalysis",

abstract = "The electro-oxidation of hydrazine is important for direct hydrazine fuel cells and for fundamental understanding of electrocatalysis in the nitrogen cycle. In this Review, we discuss electrocatalysis of the hydrazine oxidation reaction (HzOR), spanning a vast range of metal surfaces, nanoparticles, atomically dispersed ions, organometallic macrocycles, and enzymes. Emphasis is given to structure-activity correlations and reactivity descriptors, including the formulation of the Zagal principle, an electrochemical corollary of the Sabatier principle. In addition, we identify overarching themes that span the different subfields of HzOR electrocatalysis, hoping to inspire cross-disciplinary research avenues.",

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author = "Burshtein, {Tomer Y.} and Yakov Yasman and Lisa Mu{\~n}oz-Moene and Zagal, {Jos{\'e} H.} and David Eisenberg",

note = "Publisher Copyright: {\textcopyright} 2024 American Chemical Society",

year = "2024",

doi = "10.1021/acscatal.3c05657",

language = "אנגלית",

pages = "2264--2283",

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T1 - Hydrazine Oxidation Electrocatalysis

AU - Burshtein, Tomer Y.

AU - Yasman, Yakov

AU - Muñoz-Moene, Lisa

AU - Zagal, José H.

AU - Eisenberg, David

PY - 2024

Y1 - 2024

N2 - The electro-oxidation of hydrazine is important for direct hydrazine fuel cells and for fundamental understanding of electrocatalysis in the nitrogen cycle. In this Review, we discuss electrocatalysis of the hydrazine oxidation reaction (HzOR), spanning a vast range of metal surfaces, nanoparticles, atomically dispersed ions, organometallic macrocycles, and enzymes. Emphasis is given to structure-activity correlations and reactivity descriptors, including the formulation of the Zagal principle, an electrochemical corollary of the Sabatier principle. In addition, we identify overarching themes that span the different subfields of HzOR electrocatalysis, hoping to inspire cross-disciplinary research avenues.

AB - The electro-oxidation of hydrazine is important for direct hydrazine fuel cells and for fundamental understanding of electrocatalysis in the nitrogen cycle. In this Review, we discuss electrocatalysis of the hydrazine oxidation reaction (HzOR), spanning a vast range of metal surfaces, nanoparticles, atomically dispersed ions, organometallic macrocycles, and enzymes. Emphasis is given to structure-activity correlations and reactivity descriptors, including the formulation of the Zagal principle, an electrochemical corollary of the Sabatier principle. In addition, we identify overarching themes that span the different subfields of HzOR electrocatalysis, hoping to inspire cross-disciplinary research avenues.

KW - alternative fuels

KW - electrocatalysis

KW - hydrazine

KW - nitrogen cycle

KW - Sabatier principle

KW - single atom catalysts

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JF - ACS Catalysis

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Hydrazine Oxidation Electrocatalysis

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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