Oxenoids as Homologation Partners

Longyang Dian; Ilan Marek

doi:10.1002/9783527830237.ch7

Oxenoids as Homologation Partners

Longyang Dian, Ilan Marek

Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

Abstract

Homologation reactions with oxenoids have been less studied than their carbon and nitrogen counterparts, carbenoids and nitrenoids, respectively. It has been mainly restricted to the stereoretentive oxidation of vinyl metal and cyclopropyl metal, leading to the formation of stereodefined enolates and cyclopropanols that could be subsequently used for the creation of stereogenic centers and in particular for the formation of quaternary carbon stereocenters, demonstrating their potential for the construction of complex skeletons from these simple and readily available substrates.

Original language	English
Title of host publication	Homologation Reactions
Subtitle of host publication	Reagents, Applications, and Mechanisms: Volume 1 and 2
Pages	287-308
Number of pages	22
Volume	1-2
ISBN (Electronic)	9783527830237
DOIs	https://doi.org/10.1002/9783527830237.ch7
State	Published - 1 Jan 2023

Keywords

Ambiphilicity
Homologation
Oxenoids
Quaternary stereocenters

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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10.1002/9783527830237.ch7

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KW - Quaternary stereocenters

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Oxenoids as Homologation Partners

Abstract

Keywords

ASJC Scopus subject areas

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