Application of nuclear magnetic resonance to the study of acid-base equilibria

Ernest Grunwald; A. Loewenstein; S. Meiboom

doi:10.1063/1.1743803

Application of nuclear magnetic resonance to the study of acid-base equilibria

Ernest Grunwald, A. Loewenstein, S. Meiboom

Research output: Contribution to journal › Article › peer-review

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Abstract

Acid-base equilibria in aqueous solutions of methylamine, dimethylamine, and trimethylamine have been studied by nuclear magnetic resonance. It is shown that the chemical shift of the methyl protons is a linear function of the concentration ratio of acid to base plus acid. The NMR spectrum of tetramethylammonium ion is also given.

Original language	English
Pages (from-to)	641-642
Number of pages	2
Journal	The Journal of Chemical Physics
Volume	27
Issue number	3
DOIs	https://doi.org/10.1063/1.1743803
State	Published - 1957
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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title = "Application of nuclear magnetic resonance to the study of acid-base equilibria",

abstract = "Acid-base equilibria in aqueous solutions of methylamine, dimethylamine, and trimethylamine have been studied by nuclear magnetic resonance. It is shown that the chemical shift of the methyl protons is a linear function of the concentration ratio of acid to base plus acid. The NMR spectrum of tetramethylammonium ion is also given.",

author = "Ernest Grunwald and A. Loewenstein and S. Meiboom",

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doi = "10.1063/1.1743803",

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AU - Grunwald, Ernest

AU - Loewenstein, A.

AU - Meiboom, S.

PY - 1957

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N2 - Acid-base equilibria in aqueous solutions of methylamine, dimethylamine, and trimethylamine have been studied by nuclear magnetic resonance. It is shown that the chemical shift of the methyl protons is a linear function of the concentration ratio of acid to base plus acid. The NMR spectrum of tetramethylammonium ion is also given.

AB - Acid-base equilibria in aqueous solutions of methylamine, dimethylamine, and trimethylamine have been studied by nuclear magnetic resonance. It is shown that the chemical shift of the methyl protons is a linear function of the concentration ratio of acid to base plus acid. The NMR spectrum of tetramethylammonium ion is also given.

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JO - The Journal of Chemical Physics

JF - The Journal of Chemical Physics

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Application of nuclear magnetic resonance to the study of acid-base equilibria

Abstract

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